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Hiroaki Kurouchi
Hiroaki Kurouchi
Research Foundation Itsuu Laboratory
Verified email at itsuu.or.jp
Title
Cited by
Cited by
Year
Activation of electrophilicity of stable Y-delocalized carbamate cations in intramolecular aromatic substitution reaction: evidence for formation of diprotonated carbamates …
H Kurouchi, K Kawamoto, H Sugimoto, S Nakamura, Y Otani, T Ohwada
The Journal of Organic Chemistry 77 (20), 9313-9328, 2012
592012
Cyclization of arylacetoacetates to indene and dihydronaphthalene derivatives in strong acids. Evidence for involvement of further protonation of o, o-diprotonated β-ketoester …
H Kurouchi, H Sugimoto, Y Otani, T Ohwada
Journal of the American Chemical Society 132 (2), 807-815, 2010
532010
Protonation Switching to the Least‐Basic Heteroatom of Carbamate through Cationic Hydrogen Bonding Promotes the Formation of Isocyanate Cations
H Kurouchi, A Sumita, Y Otani, T Ohwada
Chemistry–A European Journal 20 (28), 8682-8690, 2014
322014
Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity
H Kurouchi, DA Singleton
Nature chemistry 10 (2), 237-241, 2018
312018
Controlling selectivity by controlling energy partitioning in a thermal reaction in solution
H Kurouchi, IL Andujar-De Sanctis, DA Singleton
Journal of the American Chemical Society 138 (44), 14534-14537, 2016
252016
Synthesis of medium-ring-sized benzolactams by using strong electrophiles and quantitative evaluation of ring-size dependency of the cyclization reaction rate
H Kurouchi, T Ohwada
The Journal of Organic Chemistry 85 (2), 876-901, 2019
242019
Facile Synthesis of 5-to 7-Membered Benzolactam Compounds via Strongly Facilitated Electrophilic Aromtic Substitution Reaction
H Kurouchi, Y Otani, T Ohwada
Heterocycles: an international journal for reviews and communications in …, 2016
242016
Acid‐Promoted Chemoselective Introduction of Amide Functionality onto Aromatic Compounds Mediated by an Isocyanate Cation Generated from Carbamate
A Sumita, H Kurouchi, Y Otani, T Ohwada
Chemistry–An Asian Journal 9 (10), 2995-3004, 2014
162014
Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts, and Kinetics of Activation by Carbenium Ions and by B(C6F5)3
G Berionni, H Kurouchi, L Eisenburger, H Mayr
Chemistry–A European Journal 22 (32), 11196-11200, 2016
112016
Potassium Base‐Catalyzed Michael Additions of Allylic Alcohols to α, β‐Unsaturated Amides: Scope and Mechanistic Insights
M Sai, H Kurouchi
Advanced Synthesis & Catalysis 363 (14), 3585-3591, 2021
92021
Phenylation reaction of α-acylnitromethanes to give 1, 2-diketone monooximes: involvement of carbon electrophile at the position α to the nitro group
M Takamoto, H Kurouchi, Y Otani, T Ohwada
Synthesis, 4129-4136, 2009
62009
Diprotonative stabilization of ring-opened carbocationic intermediates: conversion of tetrahydroisoquinoline to triarylmethanes
H Kurouchi
Chemical communications 56 (59), 8313-8316, 2020
52020
Enhancement of the carbamate activation rate enabled syntheses of tetracyclic benzolactams: 8-oxoberbines and their 5-and 7-membered C-ring homologues
H Kurouchi
Organic & Biomolecular Chemistry 19 (3), 653-658, 2021
22021
Highly Stereoselective Formation of a Spiro Center by a 1, 4-Addition/Elimination Reaction of 3, 5-Difluorocyclohexa-2, 5-dienones
M Morita, H Kurouchi, N Nemoto
Synlett 33 (06), 589-583, 2022
2022
Unusual KIE for ring-opening of short-lived intermediate formed by PCET reaction
S Alvi, D Singleton, H Kurouchi
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 258, 2019
2019
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